2. The Freshman

Blair, who is determined to maintain her "Queen Bee" status in college, embarks on her first day at New York University, along with Dan and Vanessa. Unfortunately, Georgina turns up as Blair's roommate in the dorms, determined to make Blair a social outcast. Serena begins to have second thoughts about going to Brown after her summer in Europe. Meanwhile, Nate and Bree decide to explore their relationship further, knowing full well it could cause tension between their families who are political rivals. In this episode, Leighton Meester 's collaboration with Cobra Starship, " Good Girls Go Bad ", is featured. Title reference: The 1990 film of the same name.